The Photovoltaic Effect

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The photovoltaic effect is the creation of electric current or voltage through a material upon exposure to light. It is a physical and chemical phenomenon in response to the transfer of energy from photons.

A collection of Photovoltaic cells, also known as a Solar Panel


The Main Idea

The photovoltaic effect is directly related to The Photoelectric Effect, but they are different processes. When light strikes a material surface, the electrons present in the valence band absorb the energy from the photons energy and, being excited, jump to the conduction band and become free. The material is composed of crystallized atoms that are ionized and create an electric imbalance, that drives the electrons. These highly excited electrons diffuse and some reach a junction where they are accelerated into a different material by an electrode. This generates an electric current, so some of the light energy can be converted into electric energy. This current can then be used to power an appliance.

A Mathematical Model

This expression defines the light-generated current in a photovoltaic cell, IL, as a function of solar radiation and the temperature of the cell. ST represents the intitial solar radiation, and ST,r denotes the reflected solar radiation. Tc and Tc,r are the cell temperatures before and after irradiation. IL,r is light-generated current at reference conditions, and μIsc is coefficient of temperature at short circuit current. The cell initial temperature Tc can be computed from the ambient reference temperature.